(with to:) located diagonally across from something, especially across an intersection(adverb)
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Use "kitty-corner" in a sentence
"As I retook my place on the love seat, he sat down near the end of the couch again, kitty-corner from me."
"His blotchy picture on the front next to sneering Cheney, & under Ann Coulter (he only wishes that were true in real life) and kitty-corner from Bush (obviously in the middle of a lie because his lips are open) was perfection."
"The man in the window of the building kitty-corner to the senate building knew Tarsonis City well."